Flexible allocation and space management in storage systems

In this dissertation, we examine some of the challenges faced by the emerging networked storage systems. We focus on two main issues. Current file systems allocate storage statically at the time of their creation. This results in many suboptimal scenarios, for example: (a) space on the disk is not allocated well across multiple file systems, (b) data is not organized well for typical access patterns. We propose Virtual Allocation for flexible storage allocation. Virtual allocation separates storage allocation from the file system. It employs an allocate-on-write strategy, which lets applications fit into the actual usage of storage space without regard to the configured file system size. This improves flexibility by allowing storage space to be shared across different file systems. We present the design of virtual allocation and an evaluation of it through benchmarks based on a prototype system on Linux. Next, based on virtual allocation, we consider the problem of balancing locality and load in networked storage systems with multiple storage devices (or bricks). Data distribution affects locality and load balance across the devices in a networked storage system. We propose user-optimal data migration scheme which tries to balance locality and load balance in such networked storage systems. The presented approach automatically and transparently manages migration of data blocks among disks as data access patterns and loads change over time. We built a prototype system on Linux and present the design of user-optimal migration and an evaluation of it through realistic experiments

Control of size and physical properties of graphene oxide by changing the oxidation temperature

The size and the physical properties of graphene oxide sheets were controlled by changing the oxidation temperature of graphite. Graphite oxide (GO) samples were prepared at different oxidation temperatures of 20 degrees C, 27 degrees C and 35 degrees C using a modified Hummers' method. The carbon-to-oxygen (C/O) ratio and the average size of the GO sheets varied according to the oxidation temperature: 1.26 and 12.4 mu m at 20 degrees C, 1.24 and 10.5 mu m at 27 degrees C, and 1.18 and 8.5 mu m at 35 degrees C. This indicates that the C/O ratio and the average size of the graphene oxide sheets respectively increase as the oxidation temperature decreases. Moreover, it was observed that the surface charge and optical properties of the graphene oxide sheets could be tuned by changing the temperature. This study demonstrates the tunability of the physical properties of graphene oxide sheets and shows that the properties depend on the functional groups generated during the oxidation process.clos

Analytical Modeling of Rheological Postbuckling Behavior of Wood-Based Composite Panels Under Cyclic Hygro-Loading

This study was conducted to develop analytical models to predict postbuckling behavior of woodbased composite panels under cyclic humidity conditions. Both the Rayleigh method and von Karman theory of nonlinear plate with imperfection were used to obtain a closed form solution to the hygrobuckling and postbuckling. In addition, mechano-sorptive creep effects were also taken into account for the derivation of analytical models. The closed-form solutions derived for both isotropic and orthotropic materials showed a good agreement with the experimental results in terms of the center deformation of hardboard, especially in the case of the edge movements. The unrecovery deformation was much greater at the first cycle and then decreased as the number of cyclic hygro-loading increased

Optimum Design of Quenching Capacitor Integrated Silicon Photomultipliers for TOF-PET Application

AbstractThe prototype SiPM was designed and fabricated for MRI compatible PET using the customized CMOS process at National Nanofab Center in KAIST. The SiPM was designed to have a size of 3x3 mm2 composed of micro-cells of 65x65μm2 with a fill factor of 68%. The size of a micro-cell was determined by optimization between the photon detection efficiency (PDE) and the dynamic range for the photons of 511 keV from LYSO crystal. In the micro-cell structure, a specially designed quenching capacitor (QC) is added parallel to quenching resistor using the Metal-Insulator-Metal (MIM) process. This QC integrated SiPMs (QC-SiPM) was devised to realize rapid response of output pulses and to enhance the timing resolution of SiPM. Coincidence timing resolution of PET detectors depends on the output pulse shapes which are the convolution of the intrinsic pulse shape of scintillation crystals and the single photon pulse shape at the micro-cell in a SiPM. A quenching capacitor parallel to a quenching resistor provides a fast current path at the beginning stage of avalanche process, than reduces rising time of single photon pulse shape. In this study the rise time of the QC-SiPM signal was analyzed to be 22.5ns while that for the regular SiPM was 34.3ns

Vortex-antivortex pair driven magnetization dynamics studied by micromagnetic simulations

The magnetization dynamics approaching an equilibrium vortex state from an initial nonequilibrium state under zero magnetic field in a circular shaped Fe disk with thickness of 5 nm and a diameter of 1200 nm were studied. Starting from the initial random configuration of in-plane magnetizations, a great number of vortex and antivortex pairs energetically favorable to form were generated at a lot of nucleation sites. It was found that the sites propagated and then were annihilated by their attractive interactions during the relaxation dynamic process. The study shows that temporal magnetization evolutions can be dominated by the nucleation of the vortex and antivortex pairs, followed by their propagation and annihilation.open222

Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation

Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H_2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations